The third major source of air pollution is automotive emissions. The emissions from the internal combustion engine were not an appreciable problem years ago because of the small number of registered vehicles and the nation's small highway system. However, during the early 1950's, the trend of the American people was to move from the cities to the surrounding suburbs. This caused an immediate problem in transportation because the majority of suburbs were not afforded mass transit conveniences. This lack of transportation created an attractive market for the automobile manufacturers, which resulted in a dramatic increase in the number of vehicles produced and sold, along with a marked increase in highway construction between cities and the suburbs. Multivehicle families emerged with a growing emphasis placed on an individual vehicle per family member. As the increase in vehicle ownership and usage occurred, so did pollutant levels in and around the cities, as suburbanites drove daily to their businesses and employment, returning at the end of the day to their homes in the suburbs.
It was noted that a fog and smoke type haze was being formed and at times, remained in suspension over the cities, taking time to dissipate. At first this "smog", derived from the words "smoke" and "fog", was thought to result from industrial pollution but it was determined that automobile emissions shared the blame. It was discovered that when normal automobile emissions were exposed to sunlight for a period of time, complex chemical reactions would take place.
It is now known that smog is a photo chemical layer which develops when certain oxides of nitrogen (NOx) and unburned hydrocarbons (HC) from automobile emissions are exposed to sunlight. Pollution was more severe when smog would become stagnant over an area in which a warm layer of air settled over the top of the cooler air mass, trapping and holding the cooler mass at ground level. The trapped cooler air would keep the emissions from being dispersed and diluted through normal air flows. This type of air stagnation was given the name "Temperature Inversion".