The third major source of air pollution is automotive emissions. The emissions from the internal combustion engines were not an appreciable problem years ago because of the small number of registered vehicles and the nation's small highway system. However, during the early 1950's, the trend of the American people was to move from the cities to the surrounding suburbs. This caused an immediate problem in transportation because the majority of suburbs were not afforded mass transit conveniences. This lack of transportation created an attractive market for the automobile manufacturers, which resulted in a dramatic increase in the number of vehicles produced and sold, along with a marked increase in highway construction between cities and the suburbs. Multi-vehicle families emerged with a growing emphasis placed on an individual vehicle per family member. As the increase in vehicle ownership and usage occurred, so did pollutant levels in and around the cities, as suburbanites drove daily to their businesses and employment, returning at the end of the day to their homes in the suburbs.
It was noted that a smoke and fog type haze was being formed and at times, remained in suspension over the cities, taking time to dissipate. At first this "smog," derived from the words "smoke" and "fog," was thought to result from industrial pollution but it was determined that automobile emissions shared the blame. It was discovered that when normal automobile emissions were exposed to sunlight for a period of time, complex chemical reactions would take place.
It is now known that smog is a photo chemical layer, which develops when certain oxides of nitrogen (NOx) and unburned hydrocarbons (HC) from automobile emissions are exposed to sunlight. Pollution was more severe when smog would become stagnant over an area in which a warm layer of air settled over the top of the cooler air mass, trapping and holding the cooler mass at ground level. The trapped cooler air would keep the emissions from being dispersed and diluted through normal air flows. This type of air stagnation was given the name "Temperature Inversion."
In normal weather situations, surface air is warmed by heat radiating from the earth's surface and the sun's rays. This causes it to rise upward, into the atmosphere. Upon rising, it will cool through a convection type heat exchange with the cooler upper air. As warm air rises, the surface pollutants are carried upward and dissipated into the atmosphere.
When a temperature inversion occurs, we find the higher air is no longer cooler, but is warmer than the surface air, causing the cooler surface air to become trapped. This warm air blanket can extend from above ground level to a few hundred or even a few thousand feet into the air. As the surface air is trapped, so are the pollutants, causing a severe smog condition. Should this stagnant air mass extend to a few thousand feet high, enough air movement with the inversion takes place to allow the smog layer to rise above ground level but the pollutants still cannot dissipate. This inversion can remain for days over an area, with the smog level only rising or lowering from ground level to a few hundred feet high. Meanwhile, the pollutant levels increase, causing eye irritation, respiratory problems, reduced visibility, plant damage and in some cases, even disease.
This inversion phenomenon was first noted in the Los Angeles, California area. The city lies in terrain resembling a basin and with certain weather conditions, a cold air mass is held in the basin while a warmer air mass covers it like a lid.
Because this type of condition was first documented as prevalent in the Los Angeles area, this type of trapped pollution was named Los Angeles Smog, although it occurs in other areas where a large concentration of automobiles are used and the air remains stagnant for any length of time.
Consider the internal combustion engine as a machine in which raw materials must be placed so a finished product comes out. As in any machine operation, a certain amount of wasted material is formed. When we relate this to the internal combustion engine, we find that through the input of air and fuel, we obtain power during the combustion process to drive the vehicle. The by-product or waste of this power is, in part, heat and exhaust gases with which we must dispose.
The heat from the combustion process can rise to over 4000°F (2204°C). The dissipation of this heat is controlled by a ram air effect, the use of cooling fans to cause air flow and a liquid coolant solution surrounding the combustion area to transfer the heat of combustion through the cylinder walls and into the coolant. The coolant is then directed to a thin-finned, multi-tube radiator, from which the excess heat is transferred to the atmosphere by 1 of the 3 heat transfer methods, conduction, convection or radiation.
The cooling of the combustion area is an important part in the control of exhaust emissions. To understand the behavior of the combustion and transfer of its heat, consider the air/fuel charge. It is ignited and the flame front burns progressively across the combustion chamber until the burning charge reaches the cylinder walls. Some of the fuel in contact with the walls is not hot enough to burn, thereby snuffing out or quenching the combustion process. This leaves unburned fuel in the combustion chamber. This unburned fuel is then forced out of the cylinder and into the exhaust system, along with the exhaust gases.
Many attempts have been made to minimize the amount of unburned fuel in the combustion chambers due to quenching, by increasing the coolant temperature and lessening the contact area of the coolant around the combustion area. However, design limitations within the combustion chambers prevent the complete burning of the air/fuel charge, so a certain amount of the unburned fuel is still expelled into the exhaust system, regardless of modifications to the engine.