Safety glasses should be worn at all times when working on or near the exhaust system. Older exhaust systems will almost always be covered with loose rust particles, which will shower you when disturbed. These particles could injure your eye.
Whenever working on the exhaust system always keep the following in mind:
Check the complete exhaust system for open seams, holes loose connections, or other deterioration which could permit exhaust fumes to seep into the passenger compartment.
The exhaust system is usually supported by free-hanging rubber mountings, which permit some movement of the exhaust system, but does not permit transfer of noise and vibration into the passenger compartment. Do NOT replace the rubber mounts with solid ones.
Before removing any component of the exhaust system, ALWAYS squirt a liquid rust dissolving agent onto the fasteners for ease of removal. It may even be wise to spray the fasteners and allow them to sit overnight.
Allow the exhaust system to cool sufficiently before spraying a solvent exhaust fasteners. Some solvents are highly flammable and could ignite when sprayed on hot exhaust components.
Annoying rattles and noise vibrations in the exhaust system are usually caused by misalignment of the parts. When aligning the system, leave all bolts and nuts loose until all parts are properly aligned, then tighten, working from front to rear.
When installing exhaust system parts, make sure there is enough clearance between the hot exhaust parts and pipes and hoses that would be adversely affected by excessive heat. Also make sure there is adequate clearance from the floor pan to avoid possible overheating of the floor.